The correct option is C Ionic product of water at 25∘C is 10−14
Option A : Kc×[H2O]=Kw, we know that concentration of water at 25∘C or 298K is 100018 M=55.55 M∴Kc<Kw
Option B: Effect of temperature on Kw:
The ionic product of water Kw increases with increase of temperature. The dissociation of water molecule into it's ions is an endothermic reaction.
2H2O(l)⇌H3O+(aq) + OH−(aq.)ΔH>0
By Le Chatelier's principle, increase in the temperature will shift the equilibrium in forward direction. So more ions are formed, and Kw increases.
Kw∝T
So, ionic product is greater at 373 K than at 298 K
Option C:
Kw (at 25∘C)=[H+][OH−]=10−14