Which of the following statements is/are wrong for the following reactions?
P4+5O2→P4O10 P4+3O2→P4O6
1.24 g of P4 reacts with 8.0 g of O2.
A
P4 is the limiting quantity
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B
O2 is the limiting quantity
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C
Mass of P4O10 obtained is 2.2 g
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D
Mass of P4O6 obtained is 2.84 g
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Solution
The correct options are BO2 is the limiting quantity C Mass of P4O10 obtained is 2.2 g D Mass of P4O6 obtained is 2.84 g nP4=1.2431×4=0.01mol,nO2=832=0.25mol
In reaction (i),
Moles of O2 required =(0.01molP4)(5molO2molP4)
=0.01×5=0.05mol
Since O2 is in excess amount.
Therefore, P4 is the limiting quantity.
Molecular weight P4O10=284g
0.01 mol of P4 produces = 0.01 mol of P4O10
So P4O10 in terms of mass =0.01×284=2.84g
Molecular weight of P4O6=220
Weight of P4O6 produced =(0.01molP4)(1molP4O6molP4O6)×MP4O6