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Question

Which of the following statements is/are wrong for the following reactions?


P4+5O2P4O10
P4+3O2P4O6

1.24 g of P4 reacts with 8.0 g of O2.

A
P4 is the limiting quantity
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B
O2 is the limiting quantity
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C
Mass of P4O10 obtained is 2.2 g
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D
Mass of P4O6 obtained is 2.84 g
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Solution

The correct options are
B O2 is the limiting quantity
C Mass of P4O10 obtained is 2.2 g
D Mass of P4O6 obtained is 2.84 g
nP4=1.2431×4=0.01 mol, nO2=832=0.25 mol

In reaction (i),
Moles of O2 required =(0.01 mol P4)(5 mol O2mol P4)

=0.01×5=0.05 mol

Since O2 is in excess amount.

Therefore, P4 is the limiting quantity.

Molecular weight P4O10=284 g

0.01 mol of P4 produces = 0.01 mol of P4O10

So P4O10 in terms of mass =0.01×284=2.84g

Molecular weight of P4O6=220

Weight of P4O6 produced =(0.01 mol P4)(1mol P4O6mol P4O6)×MP4O6
=0.01×220=2.2g

Hence options B,C & D are correct.

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