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Question

Which of the following statements is incorrect in case of Hofmann bromamide degradation?

A
Reaction is useful for decreasing length of carbon chain by one carbon atom.
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B
It gives tertiary amine.
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C
It gives primary amine.
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D
Aqueous or alcoholic KOH is used with bromine.
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Solution

The correct option is C It gives tertiary amine.
The statement (B), 'It gives tertiary amine' is an incorrect statement.

The correct statement is, 'It gives primary amine'.

RCONH2+Br2+4NaOHRNH2+Na2CO3+2NaBr+2H2O

Option B is correct.

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