Which of the following statements is incorrect regarding physisorption?
A
It occurs because of van der Waals forces
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B
Liquefiable gases are adsorbed more easily
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C
Enthalpy of adsorption (ΔHadsorption) is high and negative
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D
Enthalpy of adsorption (ΔHadsorption) is low and positive
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Solution
The correct options are C Enthalpy of adsorption (ΔHadsorption) is high and negative D Enthalpy of adsorption (ΔHadsorption) is low and positive For physisorption, the enthalpy of adsorption (ΔHadsorption) is low and negative. Its value is -20 to -40 kJ/mol.
Note: Physisorption occurs because of the presence of van der Waals forces between adsorbent and adsorbate molecules.
Liquefiable gases are adsorbed more easily as they have strong intermolecular attractive forces.