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Question

Which of the following statements is incorrect with respect to physisorption?

A
The forces involved are van der Waal's forces
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B
More easily liquifiable gases are adsorbed easily
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C
Under high pressure it results into multi-molecular layer on adsorbent surface
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D
ΔHadsorption is low and +ve
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Solution

The correct option is D ΔHadsorption is low and +ve
Adsorption is always exothermic therefore ΔH is always negative.

Physical adsorption is an exothermic process (i.e.,ΔH=ve) but its value is quite low because the attraction of gas molecules and solid surface is weak van der Waals forces.

Hence, option D is an incorrect statement.

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