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Question

Which of the following statements is not correct for a galvanic cell ?

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Solution

Galvanic cell is also known as Voltaic cell. It converts the chemical energy liberated during the reaction to electrical energy. The chemical reaction will be a spontaneous reaction.

In a electrochemical cell, the process of oxidation and reduction takes place simultaneously within the system. The metal strip in the cell is known as electrode.
Based on the tendency to oxidise and reduce, electrode is classified as cathode and anode.
Anode is a metal rod where oxidation reaction is takes place.
Cathode is a metal rod where reduction reaction is takes place.
Eg: Daniel cell (Galvanic cell)

At anode: \(Zn \text{ rod in } ZnSO_4 \text{ solution}\)
At cathode: \(Cu \text{ rod in } CuSO_4 \text{ solution}\)
\(Zn (s) \rightarrow Zn^{2+}(aq) + 2e^-~~~ (\text{at anode})\)
\(Cu^{2+}(aq) + 2e^- \rightarrow Cu (s)~~~ (\text{at cathode})\)
Hence, statement (c) is incorrect.

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