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Question

Which of the following statements is not correct regarding ethylamine and aniline?

A

Each has aNH2 group

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B
Both dissolve in HCl
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C
Each reacts with a mixture of CHCl3 and KOH to form a bad smelling compound
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D
Each reacts with HNO2 to give a hydroxy compound
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Solution

The correct option is D Each reacts with HNO2 to give a hydroxy compound


(a) Both contains — NH2 group.
(b) Both are dissolved in HCl to form salt as a product.

C2H5¨NH2+CHCl3chloroform+3KOHC2H5NCethyl isocyanide+3KCl+3H2O

(c)
Ethyl isocyanide and phenyl isocyanide are bad smelling compounds.

C2H5¨NH2+HNO2C2H5OH+N2+H2O

(d)

Therefore correct option is (d).

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