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Question

Which of the following substances acts as an oxidising as well as a reducing agent

A
Na2O
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B
SnCl2
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C
Na2O2
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D
NaNO2
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Solution

The correct option is D NaNO2
NaNO2 (Sodium nitrite) act both as oxidising as well as reducing agent because in it N atom is in +3 oxidation state (intermediate oxidation state) Oxidising property
2NaNO2+2KI+2H2SO4Na2SO4+K2SO4+2NO+2H2O+I2
Reducing property
H2O2+NaNO2NaNO3+H2O.

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