The correct option is A L.P.G.
The substance that has the highest inflammability and can be burnt most easily will have the lowest ignition temperature.
Among the given options, L.P.G. is the easiest to burn. Even a small spark can ignite it.
Coal and wood need a higher temperature to ignite.
Sand is a non-combustible substance and does not burn easily.
Therefore, L.P.G is the most inflammable substance and has the lowest ignition temperature among the given options.