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Question

Which of the following substances would you expect to require the most energy while vaporizing at 1.0 atm pressure?

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A
Neon
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B
Methanol
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C
Ammonia
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D
Water
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E
Benzene
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Solution

The correct option is D Water
Since ΔHrxn is maximum from the table i.e. 40.7kJ/mol the energy required for vaporising water will be higher than the others.
Enthalpy of reaction (ΔHrxn) is the change in enthalpy when a substance is transformed.
i.e ΔHrxn = energy required (added) to break the bonds of reactants - energy released to make products bonds
From the table, since ΔHrxn for water is more than others i.e. 40.7 KJ/mol. Hence water will require most energy while vaporizing at 1 atm.

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