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Question

Which of the following transitions in hydrogen atoms emit photons of the highest frequency?


A

n=1 to n=2

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B

n=2 to n=1

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C

n=2 to n=6

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D

n=6 to n=2

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Solution

The correct option is B

n=2 to n=1


Explanation of the correct option:

(B) n=2 to n=1

  • The highest frequency emission will be of maximum energy difference.
  • The greater the energy difference gets by closer the n.
  • The greater the energy difference results in an emitted photons of greater energy and therefore higher frequency and shorter wavelength.

Explanation of incorrect options:

(A) n=1 to n=2

  • When an electron jumps from n=1 to n=2, it absorbs a photon of ultraviolet light.

(C) n=2 to n=6

  • When an electron jumps from n=2 to n=6, it absorbs a photon of ultraviolet light.

(D) n=6 to n=2

  • When an electron jumps from n=6 to n=2, it emits photons of ultraviolet light.
  • In this emission, frequency is not higher than the frequency emission during n=2 to n=1.
  • Because the distance between n=6 to n=2 is more.

Hence, option (B) is correct., n=2 to n=1 transitions in hydrogen atoms emit photons of the highest frequency.


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