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Question

Which of the following two are iso-structural ?

A
XeF2,IF2
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B
NH3,BF3
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C
CO32,SO32
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D
PCl5,ICl5
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Solution

The correct option is B XeF2,IF2
Compounds having same shape with same hybridisation of the central atom are called isostructural. Both XeF2 and IF2 are linear species with sp3d hybridisation of central atom.

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