The correct option is D W=31.4 J
Since it is a cyclic process, and internal energy is a state function, hence dU=0, for the same reason, `dH=0`.
Also from the first law of thermodynamics,
q=ΔU+(−W)⇒q=−W
Also, W = area covered by sphere = πr2
=π[(V2−V1)2]2=π×(20)222=100π=100×3.14=314 J