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Question

Which of the following will be most reactive for SN1 reaction?

A
(CH3)3CCl
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B
(CH3)2CHCl
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C
(CH3)2NCH2Cl
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D
(CH3)3CBr
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Solution

The correct option is A (CH3)3CCl
Solution
Alkyl group are electron giving groups therefore it stabilises the Positive charge of C atom to which halide is connected.
Therefore that compound become most reactive
Hence Option A and B are more reactive than B,C because A,B have 3 alkyl groups present .
Among A and B , Option A is more reactive because it has more electronegative halide than option B
The correct option is A

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