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Question

Which of the following will form negatively charged colloidal solution?

A
100 mL 0.1 M AgNO3 +100 mL 0.1 M KI
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B
100 mL 0.2 M AgNO3 +100 mL 0.1 M KI
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C
100 mL 0.1 M AgNO3 +100 mL 0.2 M KI
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D
100 mL 0.2 M AgNO3 +200 mL 0.1 M KI
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Solution

The correct option is C 100 mL 0.1 M AgNO3 +100 mL 0.2 M KI

Milli moles of AgNO3=100×0.1=10
Milli moles of KI=100×0.2=20
KI is in excess.

AgNO3(aq)+KI(aq)AgI(s)+AgNO3(aq)
AgI gets precipitated.
The precipitated silver iodide adsorbs iodide ions (I) from the dispersion medium and negatively charged colloidal sol is formed AgI/I

Therefore, correct option is (c)

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