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Question

Which of the following will give acetic anhydride?

A
Acetyl chloride is heated with sodium acetate in presence of pyridine.
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B
Acetyl chloride is heated with sodium acetate in presence of HCl.
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C
Acetyl chloride is heated with ethyl acetate in presence of pyridine.
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D
Acetyl chloride is heated with ethyl acetate in presence of HCl.
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Solution

The correct option is A Acetyl chloride is heated with sodium acetate in presence of pyridine.
Acetyl chloride is heated with sodium acetate in presence of pyridine to obtain acetic anhydride.
CH3COCl+NaOOCCH3pyridineheat−−−−−−−CH3COOCOCH3+NaCl

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