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Question

Which of the following will have maximum flocculation value for arsenic sulphide sol?

A
BaCl2
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B
NaCl
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C
KCl
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D
AlCl3
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Solution

The correct option is D NaCl
To coagulate negative sol of As2S3, the coagulation power of different cations decrease in the order Al3+>Ba2+>K+>Na+.
Hence, the flocculation value increases in the order Al3+<Ba2+<K+<Na+
The flocculating values (in milli moles/litre) of Al3+<Ba2+<K+<Na+ are 0.093, 0.69, 50 and 51 respectively.

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