Which of the following will have optical isomers without having geometrical isomers?

[C o (e n)_{3}]^{3 +}

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[C r (o x)_{3}]^{3 -}

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[F e (d i p y)_{3}]^{2 +}

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all of these

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Solution

The correct option is D all of these
$M (A A)_{3}$ type compound show optical isomerism.
But since ligands are same so no cis-trans exists.

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[P t (N H_{3}) (B r) (C l) (p y)]

[C o (e n)_{3}]^{3 +}

[C r (o x)_{3}]^{3 -}

The d and l isomer of [Co(en)₃]³⁺are type of:

[C r (O X)_{3}]^{3 -}

[C o C l_{3} (N H_{3})_{3}]

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