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Question

Which of the following will have the most negative electron gain enthalphy and which the least negative?

A
F, Cl
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B
Cl,F
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C
Cl,S
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D
CL,P
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Solution

The correct option is A F, Cl
Halogen have highest is more negative than negative value of electron gain enthalphy ,Here Cl,F both are halogens but electron gain enthalphy of Clis more negative than F because of very small size of F which causes interelectronic repulsion among its electrons.
Cl has the most negative one.
P has the least negative one due to greater size.

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