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Byju's Answer
Standard XII
Chemistry
Curtius and Hofmann Rearrangements
Which of the ...
Question
Which of the following will not form a yellow precipitate on heating with an alkaline solution of iodine?
A
C
H
3
C
H
2
C
H
(
O
H
)
C
H
3
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B
C
H
3
O
H
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C
C
H
3
C
H
2
O
H
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D
C
H
3
C
H
(
O
H
)
C
H
3
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Solution
The correct option is
D
C
H
3
O
H
Methanol
(
C
H
3
−
O
H
)
- The iodoform test is a test for the presence of carboxyl compound with the structure.
(Refer to image 01)
and alcohols with the structure (Refer ti image 02)
- While in case of methanol, here is no beta carbon in it.
Alcohols those are having beta carbon in its they can give a methyl ketone after oxidation.
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Similar questions
Q.
Following compounds are given
(i)
C
H
3
C
H
2
O
H
(ii)
C
H
3
C
O
C
H
3
(iii)
C
H
3
−
C
|
C
H
3
H
O
H
(iv)
C
H
3
O
H
Which of the above compound(s) on being warmed with iodine solution and
N
a
O
H
, will give iodoform?
Q.
A colourless liquid
A
(
b
.
p
184
∘
C
)
is sparingly soluble in warm water to which it gives feebly alkaline reaction on treating with
N
a
N
O
2
a
n
d
d
i
l
H
C
l
in the cold solution, it yields a solution which reacts with an alkaline solution of
β
−
napthol to give an orange yellow precipitate. Compound
A
is
:
Q.
A compound have the vapour density of 29. When its aqueous alkaline solution is heated with
I
2
, yellow precipitate forms. The compound may be:
Q.
Which of the following compounds will give a yellow precipitate with iodine and alkali?
Q.
An aqueous solution of a compound
X
shows the following reactions.
(i) It decolourises an acidified
K
M
n
O
4
solution accompanied by the evolution of oxygen.
(ii) It liberates iodine from an acidified potassium iodine solution.
(iii) It gives a brown precipitate with alkaline
K
M
n
O
4
solution with the evolution of oxygen.
(iv) It removes black stains from old oil paintings.
Identify
X
.
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