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Question

Which of the following will not give aldol condensation?

A
Phenyl acetaldehyde
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B
Benzaldehyde
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C
1-Phenylpropanone
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Solution

The correct option is B Benzaldehyde
An aldol condensation is a condensation reaction in which an enol or an enolate ion reacts with a carbonyl compound to form a β-hydroxyaldehyde or β-hydroxyketone, followed by dehydration to an α,β-unsaturated aldehyde.
Aldol condensation occurs in aldehydes having α-hydrogen.
Benzaldehyde does not have α-hydrogen thus it will undergo aldol condensation. Hence correct option is (c).

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