wiz-icon
MyQuestionIcon
MyQuestionIcon
1
You visited us 1 times! Enjoying our articles? Unlock Full Access!
Question

Which of the following will react at faster rate with acetone to give a product containing


A

C6H5NH2

No worries! We‘ve got your back. Try BYJU‘S free classes today!
B

(CH3)5N

No worries! We‘ve got your back. Try BYJU‘S free classes today!
C

C6H5NHC6H5

No worries! We‘ve got your back. Try BYJU‘S free classes today!
D

C6H5NHNH2

Right on! Give the BNAT exam to get a 100% scholarship for BYJUS courses
Open in App
Solution

The correct option is D

C6H5NHNH2


The required structure can be obtained only when the reactant site has 2 available hydrogens. These are eliminated to form imine. Imines in which the nitrogen atom carries an electronegative group are usually more stable; think oximes and hydrazones.

So from the given options, we can first narrow down our choices by eliminating the primary and tertiary amines.

Among the remaining options, we pick phenyl hydrazine over aniline because it forms a more stable imine.


flag
Suggest Corrections
thumbs-up
1
Join BYJU'S Learning Program
similar_icon
Related Videos
thumbnail
lock
Synthesis of Carboxylic Acids
CHEMISTRY
Watch in App
Join BYJU'S Learning Program
CrossIcon