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Question

Which of the following will supress the ionisation of acetic acid in aqueous solution?

A
NaCl
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B
HCI
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C
KCI
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D
Unpredicatble
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Solution

The correct option is B HCI
Adding a common ion prevents the weak acid or weak base from ionizing as much as it would without the added common ion. The common ion effect suppresses the ionization of a weak acid by adding more of an ion that is a product of this equilibrium.
So addition of CH3COONa to CH3COOH increases the pH of solution but addition of NH4Cl to NH4OH decreases the pH of solution.
Here, the addition of HCl acid will suppress the ionisation of acetic acid.

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