Which of the following would not react with benzene sulphonyl chloride in aq. $N a O H$ ?

Aniline

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Methylamine

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N, N

-dimethyl aniline

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N -

methyl aniline

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Solution

The correct option is B $N, N$ -dimethyl aniline
N,N-dimethyl aniline does not contain $H$ attached to nitrogen.
Hence, it would not react with benzene sulphonyl chloride in aqueous $N a O H$ .

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The positive carbylamines test is given by
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(iii) N-methyl-O-methyl aniline (iv) p-methyl benzylamine

P h N_{2}^{+} {B r}^{-}

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