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Question

Which of the followings is incorrect?

A
According to law of mass action, rate of a chemical reaction is proportional to molar concentration of reactants.
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B
If Kc 1 then products are present predominantly at equilibrium.
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C
Catalysts increase the rate of forward reaction as well as backward reaction.
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D
Value of equilibrium constant increases with increase in temperature.
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Solution

The correct option is D Value of equilibrium constant increases with increase in temperature.

a) According to law of mass action,rate of a chemical reaction is proportional to molar concentration of reactants.

b) At equilibrium,

  • Products are present predominantly if Kc>1
  • Products are present predominantly if Kc<1



b) Though value of equilibrium constant doest not charge, catalysts increase the rate of both the forward and backward reactions.
c) lnk2k1= HR(1T11T2)
IfT2> T1,

  • K2< K1 if H>0 i.e. reaction is endothermic
  • K2< K1 if H>0 i.e. reaction is exothermic

Hence this Option is incorrect


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