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Question

Which of the given aldehydes will not give aldol condensation reactions?

(1) Propanal (2) Ethanal (3) 2.2-dimethylpropane (4) 2,2-dimethyl butanal (5) Benzaldehyde

A
1 and 4 only
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B
1 and 2 only
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C
2,3 and 4 only
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D
3,4 and 5 only
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Solution

The correct option is D 3,4 and 5 only

Aldol condensation is an organic reaction in which an enolate ion reacts with carboxyl compound in order to form a β– hydroxyaldehyde or β– hydroxyketone.The aldehyde or ketone that is going to be reacted should have an alpha hydrogen.

Following compounds will not give aldol condensation reaction

2,2-dimethyl propane its not an aldehyde or keetone

2,2-dimethyl butanal,Benzaldehyde these two compounds do not have alpha hydrogens.

Hnce option D is correct.



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