The correct option is C 3
On the absorption of a photon, an electron jumps from a lower state to a higher state and when energy is emitted, it falls from a higher to a lower state.
The lowest energy state of an atom is when n=1. So, emission of a photon is not possible for this level.
In option (b), for n=2 only one photon from n=2 to n=1 is possible.
In option (c) for an electron in n=3, three photons are possible
n=3 to n=2,n=3 to n=1,n=2 to n=1.