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Question

Which of the liquids can be separated by simple distillation method?

A
Liquids having sufficient difference in their boiling points
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B
Liquids which boil without decomposing at atmospheric pressure
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C
Liquids whose boiling points are close to each other
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D
Benzene (B.P. = 80°C) and Aniline (B.P. = 184°C)
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Solution

The correct option is D Benzene (B.P. = 80°C) and Aniline (B.P. = 184°C)
Simple distillation is applied only for volatile liquids which boil without decomposing at atmospheric pressure and contains ​non-volatile impurities.​

It can also be used for separating liquids having sufficient difference in their boiling points.

The boiling point of benzene and aniline is 80 and 184 respectively. Since, they have a huge difference in their boiling point, they can be separated by simple distillation method.

Liquids whose boiling points are close to each other can be separated by fractional distillation method.

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