The correct option is D Benzene (B.P. = 80°C) and Aniline (B.P. = 184°C)
Simple distillation is applied only for volatile liquids which boil without decomposing at atmospheric pressure and contains non-volatile impurities.
It can also be used for separating liquids having sufficient difference in their boiling points.
The boiling point of benzene and aniline is 80∘ and 184∘ respectively. Since, they have a huge difference in their boiling point, they can be separated by simple distillation method.
Liquids whose boiling points are close to each other can be separated by fractional distillation method.