The correct option is
E Nil
A prefers tea. So, from (iv), the industrialist and D prefer coffee. But, from (iii), B and the journalist prefer coffee. So, B is the industrialist and D is the journalist.
Now, A, C and advocate remain. Clearly, E is the advocate.
The horticulturist is C's brother. It can be only A. C is a physicist.
A B C D E
Profession Horticulturist Industrialist Physicist Journalist Advocate
Profession Tea Coffee Tea Coffee Tea
Since all the statements are required to analyse the given data, none of them is superfluous.