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Question

Which of the statements is/are correct ?
RRH2+P2−−−−−catalyst(A)MMPP−−−−(B)H+/H2O−−−−+(C))LiAlH4/EtOH(D)MMPP−−−−−−−−−−−(E)H+/H2O−−−−(F)

A
(C) is an equimolar mixture of two enantiomeric compound
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B
(F) is a single compound and is optically inactive
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C
(C) is a single compound and is optically inactive
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D
(F) is an equimolar mixture of two enantiomeric compound
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Solution

The correct options are
C (C) is an equimolar mixture of two enantiomeric compound
D (F) is a single compound and is optically inactive
Rule : cis compound + anti-addition of Br2 Product is racemic
trans compound + anti-addition of Br2 Product is meso (when R= R)
So, (C) is an equimolar mixture of two enantiomeric compound and (F) is a single compound and is optically inactive. Hence, options A & B are correct.

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