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Question

Which of the two tautomers is more stable?
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A
I
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B
II
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C
I=II
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D
None of these
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Solution

The correct option is B I
In oxime, nitrogen is attached to carbon by a double bond (II), whereas in nitroso form, nitrogen is attached to oxygen by a double bond(I). Greater the electronegativity difference between the atoms, stronger is the bond. Therefore nitroso form is more stable than the oximino form. Therefore, option A is correct.

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