Which of these compound can give an $N -$ nitroso amine on reaction with nitrous acid?
(I) $C_{6} H_{5} C O N H C_{2} H_{5}$ (II) $C_{2} H_{5} N H C_{2} H_{5}$ (III) $C_{6} H_{5} N H C_{2} H_{5}$ (IV) $C_{6} H_{5} N H C_{6} H_{11}$

I, I I, I I I

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I, I I I, I V

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I I, I I I, I V

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I, I I, I V

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Solution

The correct option is C $I I, I I I, I V$
Only $2^{0}$ amine gives N-nitro amine on reaction with nitrous acid and $1^{o}$ amine give alcohol.

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