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Question

Which of these is not a monomer for a high molecular mass silicone polymer?

A
Me3SiCl
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B
PhSiCl3
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C
MeSiCl3
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D
Me2SiCl2
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Solution

The correct option is A Me3SiCl
On hydrolysis, one OH group will take the place of each Cl group. If we can have at the very least 2 replaceable Cl groups,
a high molecular mass silicone polymer shall come into play.
Let us take a popular example for illustration:

Me2SiCl2+2H2OMe2Si(OH)2

The product polymerizes to yield

[OMe2SiO]n


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