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Question

Which of these statements about [Co(CN)6]3 is true :-

<!--td {border: 1px solid #ccc;}br {mso-data-placement:same-cell;}--> AIPMT 2015

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Solution

[Co(CN)6]3
Co3+=3d64s04p0
It is a octahedral species and due to presence of strong field ligand it form low spin complex.
Its electronic configuration is t62ge0g
Due strong field ligand, pairing of electrons occurs so in this complex no unpaired electron is present and it is low spin complex.

Hence, option (d) is correct.

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