The correct option is
D Concanavalin-A, morphine, codeine, vinblastin
Secondary metabolite are the organic compound which do not play a direct role in the growth and development of the organism. Concanavalin-A, morphine, codeine, vinblastin are secondary metabolite.
Concanavalin A is a carbohydrate binding protein which is obtained from the jackbean.
Codeine is a drug which is mainly used to treat a moderately or severe pain.
Morphine is a pain reviler which acts directly on the central nervous system. It is used for both acute and chronic pain.
Vinblastine is a alkaloid which is used as a drug to cure the cancer.
So, the correct answer is option D.