Which one is least reactive in a nucleophilic substitution reaction?

C H_{3} C H_{2} C l

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C H_{2} = C H C H_{2} C l

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C H_{2} = C H C l

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(C H_{3})_{3} C C l

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Solution

The correct option is D $C H_{2} = C H C l$
Vinyl chloride is least reactive for $S_{N}$ reaction due to resonance stabilisation of $C - C l$ bond.

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Which of the following is least reactive in nucleophilic substitution reaction?

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