Which one is more soluble in diethyl ether-anhydrous nbsp-alcl3N or hydrous nbsp-alcl3- nbsp-

Anhydrous AlCl3 will dissolve the diethyl ether because anhydrous nbsp;AlCl3 nbsp;is a good lewis acid. It is electron deficient. The lone pairs of diethyl ...

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Standard XII

Chemistry

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which one is ...

Question

which one is more soluble in diethyl ether,anhydrous alcl3N or hydrous alcl3?

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Solution

Anhydrous AlCl₃ will dissolve the diethyl ether because anhydrous AlCl₃ is a good lewis acid. It is electron deficient. The lone pairs of diethyl ether will be donated to the anhydrous AlCl₃ due to which it is soluble. On the other hand, hydrous AlCl₃ have the water molecules which make it poor lewis acid.
So, diethyl ether will be solube in anhydrous AlCl₃.

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