Which one of ...

Question

Which one of the following complexes will have six isomers?

[C o (e n) (N H_{3})_{2} C l_{2}] C l

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[C r (H_{2} O)_{4} C l_{2}] C l

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[C o (o x)_{3}]^{3 -}

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[C o (e n)_{2} B r_{2}] C l

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Solution

The correct option is B $[C o (e n) (N H_{3})_{2} C l_{2}] C l$
The isomers of $[C o (e n) (N H_{3})_{2} C l_{2}] C l$ ,
(i) and (ii) have cis-optical isomer also so the total isomers are $4$ geometrical and $2$ optical isomers.

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_{3}

_{4}

_{2}

_{3}

_{4}

_{2}

Number of possible isomers for the complex $[C o (e n)_{2} C l_{2}] C l$ will be (en = ethylenediamine)