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Structural Isomerism

Which one of ...

Question

Which one of the following compounds has tetrahedral geometry?

[N i (C N)_{4}]^{2 -}

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[N i C l_{4}]^{2 -}

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[P d C l_{4}]^{2 -}

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[P d (C N)_{4}]^{2 -}

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Solution

The correct option is B $[N i C l_{4}]^{2 -}$
Halides are weak field ligand so all the nickel halides are tetrahedral in geometry.

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Similar questions

Explain on the basis of valence bond theory that [Ni(CN)₄]²⁻ ion with square

planar structure is diamagnetic and the [NiCl₄]²⁻ ion with tetrahedral geometry is paramagnetic.

[N i (C N)_{4}]^{2 -}, [N i C l_{4}]^{2 -}

[N i (C O)_{4}]

[N i (C N)_{4}]^{2 -}

X e F_{4}

S F_{4}

[N i C l_{4}]^{2 -}

[P d C l_{4}]^{2 -}

[F e (H_{2} O)_{6}]^{2 +}

[F e (C N)_{6}]^{4 -}

[N i (C O)_{4}]

[N i (H_{2} O)_{4}]^{2 +}

[N i (C N)_{4}]^{2 -}

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