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Question

Which one of the following compounds is not formed in the 'catalytic cracking' of octane?

A
Pentane
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B
Butane
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C
Propene
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D
Hydrogen gas
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Solution

The correct option is C Hydrogen gas
During pyrolysis or catalytic cracking of alkanes, on strong heating at high temperature, in absence of air, higher alkanes split into lower alkanes, alkenes and hydrogen.

RHHeat−−−−−−−−−absence of oxygen(lower alkane)RH+(alkene)R=R+H2

However during catalytic cracking of octane, hydrogen gas is not obtained. Pentane, butane and propene are obtained.

Option D is correct.

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