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Question

Which one of the following compounds undergoes hydrolysis during distillations to yield hydrogen peroxide?

A
H2S2O8
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B
H2S2O6
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C
HNO3
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D
H4P2O7
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Solution

The correct option is B H2S2O8
One of the methods of preparation of H2O2 is from sulphuric acid.
Electrolysis of acidic sulphate solutions leads to the formation of peroxodisulfuric acid which then further hydrolyses to give H2O2.

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