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Question

Which one of the following compounds will give racemic mixture in SN1 reaction?

A
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B
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C
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D
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E
None of the above
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Solution

The correct option is B
Stereochemistry in nucleophilic substitution reaction arises due to presence of a chiral carbon in compound.
SN1 reaction of an optically active halide is accompanied by racemization and it give equimolar mixture of d and l forms of an optically active compound.
Only b has chiral carbon thus it will give (d) and (l) form in SN1 reaction as major product.


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