Which one of the following compounds will react with methyl magnesium iodide?

C H_{3} C H_{2} C H_{2} C H_{2} C H_{3}

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C H_{3} C H = C H - C H = C H_{2}

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C H_{3} - C \equiv C - C H_{2} C H_{3}

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C H_{3} C H_{2} C H_{2} C \equiv C H

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Solution

The correct option is D $C H_{3} C H_{2} C H_{2} C \equiv C H$
Due to the presence of acidic hydrogen (hydrogen attached to triply bonded carbon atom) terminal alkyne $(D)$ will react with methyl magnesium iodide.

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