The correct option is C V(CO)6
For Fe(CO)5, EAN=26−0+10=36. Thus, it follows EAN rule.
For V(CO)6, EAN=23−0+12=35. Thus, it does not follow EAN rule.
For K4[Fe(CN)6], EAN=26−2+12=36. Thus, it follows EAN rule.
For Mn2(CO)10, EAN=25+1+10=36. Thus, it follows EAN rule.