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Question

Which one of the following does not follow EAN rule?

A
Fe(CO)5
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B
V(CO)6
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C
K4[Fe(CN)6]
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D
Mn2(CO)10
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Solution

The correct option is C V(CO)6
For Fe(CO)5, EAN=260+10=36. Thus, it follows EAN rule.
For V(CO)6, EAN=230+12=35. Thus, it does not follow EAN rule.
For K4[Fe(CN)6], EAN=262+12=36. Thus, it follows EAN rule.
For Mn2(CO)10, EAN=25+1+10=36. Thus, it follows EAN rule.

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