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Question

Which one of the following does not give a white precipitate with silver nitrate solution?


A

[Co(NH3)5Cl]Cl2

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B

[Co(NH3)4Cl2]Cl

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C

[Co(NH3)3Cl3]

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D

[Co(NH3)6]Cl3

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Solution

The correct option is C

[Co(NH3)3Cl3]


For the precipitation of AgCl there must be free Cl- ion, the Cl- ligand have to be there in the primary coordination sphere.


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