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Question

Which one of the following does not have intermolecular H-bonding?

A
CH4
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B
H2Se
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C
N2H4
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D
H2S
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Solution

The correct options are
A CH4
B H2Se
C H2S
Condition for H-Bonding
  • Highly Electronegative atom bonded to Hydrogen molecules
    must contain High EN atom such as N, O, or F covalently bonded to Hydrogen.
    ex: HF,H2O,NH3
  • The small size of EN atom
    Smaller the size of the atom, greater will be an attraction for the bonded electron pair. In other words, a polarity of a bond between H atom and the electronegative atom should be high.
    Out of all the molecules, only N2H4 fits into the condition.

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