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Question

Which one of the following formulae represents Ostwald's dlution law for a binary electrolyte whose degree of dissociation is 'α' and concentration C?

A
K=(1α)Cα
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B
K=α2C(1α)
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C
K=(1α)Cα2
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D
K=α2(1α)C
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Solution

The correct option is B K=α2C(1α)
ABA++B
C 0 0
C(1α) Cα Cα
Ka=[A+][B][AB]
Ka=Cα×CαC(1α)=Cα21α

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