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Question

Which one of the following has the highest dipole moment?
(i)CH2Cl2(ii)CHCl3(iii)CCl4

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Solution

Dichloromethane has highest dipole moment among CH2Cl2, CHCl3 and CCl4. The decreasing order of dipole moments is CH2Cl2>CHCl3>CCl4. These molecules have tetrahedral geometry due to sp3 hybridization of carbon atom.In CCl4, the individual CCl bond dipoles cancel each other which results in zero dipole moment.
Hence, CCl4 is non polar.

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