Which one of the following has the highest dipole moment? (i)CH2Cl2(ii)CHCl3(iii)CCl4
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Solution
Dichloromethane has highest dipole moment among CH2Cl2,CHCl3 and CCl4. The decreasing order of dipole moments is CH2Cl2>CHCl3>CCl4. These molecules have tetrahedral geometry due to sp3 hybridization of carbon atom.In CCl4, the individual C−Cl bond dipoles cancel each other which results in zero dipole moment.