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Question

Which one of the following is correct with respect to molar ionic conductance of ions in aqueous solution?

A
Li+<Na+<K+<Rb+
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B
Rb+<K+<Na+<Li+
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C
Sr2+<Ca2+<Mg2+<Be2+
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D
Na+<K+<Li+<Rb+
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Solution

The correct option is A Li+<Na+<K+<Rb+
Larger is the size of the ion, smaller is the degree of hydration and larger is the molar ionic conductance. Hence, the correct order of the molar ionic conductance is Li+<Na+<K+<Rb+.

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