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Question

Which one of the following is not applicable to the phenomenon of adsorption?


A
G<0
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B
S<0
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C
H<0
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D
H>0
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Solution

The correct option is D H>0

We know,

∆G = ∆H - T ∆S

Enthalpy change during the phenomenon of adsorption is negative because, during adsorption, there is always a decrease in entropy and so to make G negative, H must be negative.
So, adsorption is an exothermic process and hence it can not have H>0.

So, option (A) is correct.


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